GEOL445  Aqueous Geochemistry

CONTENT:  This course is an introduction to the geochemical processes of surface and ground water, including concentrations of ions and organic compounds, chemical equilibria, and analytical techniques. Carbonate and clay minerals will be studied in detail. Prerequisite: CHEM120 and CHEM121. 3 hours.

OFFERED:  Spring semester, even numbered years.


Current Syllabus: SPRING 1998

Instructor: Dr. Michael May Office: 309 EST Phone: 745-6891

E-mail: michael.may@wku.edu

Office Hours: M, T, W, R, F 8:00-9:00; M, T, W 10:30-11:30

Course Time and Place: EST Room 355, TR and alternating Fridays, 11:45-12:45

Purpose and Design of the Course and Prerequisites: Geology 445 is a required course for geology majors in the Hydrology option. Chemistry 120 and 121 are prerequisites. The student should also have a working knowledge of mineralogy or crystal chemistry. The course is designed to provide an introduction to the geochemical processes of surface water and groundwater, including concentrations of ions and organic compounds, chemical equilibria, and analytical techniques. Sediment/rock/water interaction including diagenesis and weathering will be discussed. The stability of silicates, carbonates and clay minerals will be studied in detail.

Text (required): The Geochemistry of Natural Waters, Surface and Groundwater Environments, 3rd ed., James I. Drever, Prentice Hall, 1997.

** Always bring your text to class **

Course Outline

Date Day Topic Reading

Jan. 20 T The Hydrologic Cycle Chapter 1

22 W Chemical Terminology Chapter 2

27 T

29 R Guest Lecture - Common Analytical Methods

30 F Common Organic Compounds Chapter 6

Feb. 3 T

5 R The Carbonate System Chapter 3

10 T

12 R Clay Minerals and Ion Exchange Chapter 4

13 F

17 T Adsorption Chapter 5

19 R EXAM I

24 T Silicate Equilibria & Stability Diagrams Chapter 10

26 R

27 F

Mar. 3 T Kinetics of Geochemical Processes Chapter 11

5 R Weathering and Water Chemistry Chapter 12

10 T

12 R

13 F EXAM II

16-20 SPRING BREAK

24 T Weathering and Water Chemistry cont. Chapter 12

26 R Acid Deposition and the Environment Chapter 13

31 T

Apr. 2 R Isotopes Chapter 14

3 F (Literature review paper due)

7 T Evaporites and Saline Waters Chapter 15

9 R

14 T Oxidation - Reduction Equilibrium Reactions Chapter 7

16 R

17 F

21 T EXAM III

23 R Redox Conditions in Natural Waters Chapter 8

28 T

30 R Heavy Metals and Metalloids Chapter 9

May 1 F (Analytical Procedures paper due)

5 T Transport & Reaction Modeling Chapter 16

7 R

11 M FINAL EXAM - 10:30am - 12:30pm

Grading: 3 hour exams - 60%

Final exam - 15%

Literature paper - 10%

Analytical paper - 10%

Problem Solving - 5%

Exams will consist of short-answer and essay questions and some problem solving.

The literature paper will be a 5-page minimum evaluation/critique of two scientific articles, either listed as suggested readings at the end of any of the chapters of your textbook or articles of your choosing. Note that the library has GEOREF, which is similar to TOPCAT except that the specific area is geology and our library will have very few of the references given. So give yourself time to use inter-library loan if necessary. Use the same format as your textbook uses for citing references in your paper and the citation of the references at the end. This paper will be due on April 3.

The analytical paper is to cover an analytical technique of your choosing. You will choose from the various analyses that are routinely performed in the water lab on the fourth floor of this building (Ogden Environmental Lab). Any time after spring break, schedule a time with Rose Hullett (water lab manager) to be in the lab when the analysis is being performed so that you can walk through the technique. You will discuss the procedure in your paper, including a detail of the step-by-step process, repeatability/reproducibility of the test, EPA acceptable limits, the general historical development of the test with regard to how it may have changed with time as EPA limits have become stricter, and possible EPA trends for the future. One or more of you may visit the lab at one time if you have chosen the same analysis, although Rose may restrict the number. The length of this paper should be under 5 pages. It will be due on May 1.

Attendance: Attendance is mandatory. Although no points will be deducted for missing class, supplemental material not covered in the text will often be included in lectures.

Due Dates for Assignments and Exams: If you know that you will miss an exam or paper deadline, it is your responsibility to inform me before hand to explain your situation. If you miss any deadline without contacting me before the due date or scheduled exam time you will automatically waive your right to take a make-up exam or hand in a paper (i.e. no credit given for unexcused late work).


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